Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil   总被引：1，自引：0，他引：1  

Jie Liu  Chang-Qun Duan  Yi-Nian Zhu  Xue-Hong Zhang  Cheng-Xian Wang 《Environmental Geology》2007,52(8):1601-1606

Effect of chemical fertilizers (urea, NH₄Cl, Ca(NO₃)₂, KCl and KH₂PO₄) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure, it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil. Applying urea (CO(NH₂)₂) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH₄Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH₂)₂ raised the soil pH from 4.51 to 4.96, whereas NH₄Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH₂PO₄ reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual (RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH₄Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH₂PO₄ decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil.  相似文献   

Detection of station coordinate discontinuities within the Italian GPS Fiducial Network     

Nicola Perfetti 《Journal of Geodesy》2006,80(7):381-396

The Detection Identification Adaptation (DIA) procedure was applied to the coordinate time-series of some permanent GPS stations belonging to the Italian GPS Fiducial Network (IGFN), of the Italian Space Agency (ASI), to detect discontinuities and to reject outliers. The daily solutions of the stations of Cagliari, Genoa, Medicina, Noto, Turin, Perugia and Venice were computed for the period 1997.0–2003.0 using Bernese GPS software v.4.2. The data were interpolated using a model with a linear term and an annual periodic term. The parameters were estimated by least squares. The DIA procedure was organized to automatically detect discontinuities and outliers. Approximately, 70% of the discontinuities present in the coordinate time-series were identified and their magnitudes were estimated. The identified discontinuities are basically caused by equipment replacement and reference frame changes, but in a few cases the reason is still unknown. With regard to the outliers, roughly 6% of the data were rejected. These data were considered outliers on the base of the level of significance and of the power of the test adopted in this work. Except for the stations of Perugia and Venice, the estimated coordinates agree with ITRF2000 values at the 10 mm level, and the estimated velocities are within a few mm/year of the ITRF2000 values.  相似文献   

Quantifying anthropogenic influence on recent near-surface temperature change   总被引：2，自引：0，他引：2  

M. R. Allen  N. P. Gillett  J. A. Kettleborough  G. Hegerl  R. Schnur  P. A. Stott  G. Boer  C. Covey  T. L. Delworth  G. S. Jones  J. F. B. Mitchell  T. P. Barnett 《Surveys in Geophysics》2006,27(5):491-544

We assess the extent to which observed large-scale changes in near-surface temperatures over the latter half of the twentieth century can be attributed to anthropogenic climate change as simulated by a range of climate models. The hypothesis that observed changes are entirely due to internal climate variability is rejected at a high confidence level independent of the climate model used to simulate either the anthropogenic signal or the internal variability. Where the relevant simulations are available, we also consider the alternative hypothesis that observed changes are due entirely to natural external influences, including solar variability and explosive volcanic activity. We allow for the possibility that feedback processes, other than those simulated by the models considered, may be amplifying the observed response to these natural influences by an unknown amount. Even allowing for this possibility, the hypothesis of no anthropogenic influence can be rejected at the 5% level in almost all cases. The influence of anthropogenic greenhouse gases emerges as a substantial contributor to recent observed climate change, with the estimated trend attributable to greenhouse forcing similar in magnitude to the total observed warming over the 20th century. Much greater uncertainty remains in the response to other external influences on climate, particularly the response to anthropogenic sulphate aerosols and to solar and volcanic forcing. Our results remain dependent on model-simulated signal patterns and internal variability, and would benefit considerably from a wider range of simulations, particularly of the responses to natural external forcing.  相似文献   

Lake-Level Fluctuations and Small-Scale Vegetation Patterns During the Late Glacial in The Netherlands     

Johanna A. A. Bos  Sjoerd J. P. Bohncke  C. Roel Janssen 《Journal of Paleolimnology》2006,35(2):211-238

Late glacial changes in the vegetation were studied in and around a former lake on the southeastern side of a coversand ridge near Milheeze (southern Netherlands). Analyses of microfossils and macroremains and AMS ¹⁴C dating were performed on four sediment cores along a transect from sand ridge to the lake centre. Small-scale vegetation patterns and lake-level fluctuations were reconstructed in detail based on the information provided by the transect. For the first time in The Netherlands, cores along a transect within one lake were used to reconstruct the amplitude of late glacial lake-level fluctuations. Near Milheeze, a small and shallow lake was formed during the Bølling. The large increase in the water level during the Bølling and early Allerød, and the transition to more eutrophic conditions at the start of the Allerød, were probably related to the disappearance of permafrost. During the Allerød, open birch and pine woodlands developed in the area. In the lake, organic deposits accumulated, and the lake size and depth fluctuated. At the start of the Younger Dryas, higher lake water levels were recorded and woodlands became more open as a result of both a drop in the temperature and an increase in the effective precipitation. During the late Younger Dryas the lake water level dropped as the climate became drier and temperatures slightly increased. Accumulation of organic deposits in the lake ceased at the end of the Younger Dryas, which was caused by a drop in the water level in combination with the hydroseral succession process within the lake itself. The climatic signal reflected in the late glacial flora and lake-level fluctuations agree well with other published data from The Netherlands.  相似文献   

从PM10的测量推测成都市区汞污染的来源     

李奕霖  ;张成江  ;施泽明  ;郭亚杰 《辽宁气象》2007,(6):68-71

通过2007年5—6月期间测量成都市若干条剖面上大气可吸入颗粒物（PM10）中的汞含量，来推测成都市大气中汞的来源。结果表明：在12个点的测量范围内，成都市PM10的质量平均浓度为210．8μg／m^3；PM10中汞的质量平均浓度为0．36ng／m^3。公园和郊区PM10浓度和其中汞浓度均较少，可能与植被茂盛有关。由PM10中汞的分布可知，在热电厂、停用的生活垃圾堆放场和寺庙附近出现最高值。说明热电厂和生活垃圾堆放场是大气汞污染的重要次生来源。寺庙附近出现的高汞值，推测与寺庙的礼仪活动如香烛燃烧有关。  相似文献   

Paleoenvironmental analysis of a middle Wisconsinan biota site, southwestern Virginia, U.S.A.     

G. Richard Whittecar  Thomas C. Wynn  Charles S. Bartlett Jr. 《Quaternary Research》2007,68(1):133-140

The Ratcliff Site in southwestern Virginia lies in a small second-order stream valley filled with approximately 3.5 m of organic-rich deposits that contain bones of mammoth, mastodon, deer (or antelope), logs, and plant macrofossils. Radiocarbon analyses indicate the age of the organic-rich sediment ranges from > 44,000 to 29,100 ¹⁴C yr BP, a time period with no fossil remains reported in this region of the Appalachians. Analyses of field observations, textural data, organic carbon content, and plant macrofossils indicate that the organic-rich sediments contain interbedded standing-water and debris-flow deposits. Up to 6 m of oxidized debris-flow sediments bury the organic-rich sediments. The presence of Rubus parviflorus (Thimble Berry) throughout the deposit indicates the site had a boreal environment from > 44,000 to 29,100 ¹⁴C yr BP. Plant macrofossil evidence indicates the uplands had stands of spruce/jack-pine forests while the valley contained ponds and associated wetlands. Three debris flows occurred at the site between approximately 38,000 and 29,000 ¹⁴C yr BP, suggesting a recurrence interval for major storms of approximately 3000 yr, even though the apparent stability of the boreal environment implies a climate not conducive to catastrophic rainstorms. This conflicting combination of features suggests that during the middle Wisconsinan this area experienced generally cool climates, dominated by polar air masses, but was punctuated by relatively brief warm periods marked by incursions of tropical air masses.  相似文献   

Characterisation of riparian woodlands and their potential water loss in the distal Okavango Delta, Botswana     

Susan Ringrose   《Applied geography (Sevenoaks, England)》2003,23(4):281-302

An analysis is undertaken to develop techniques to remotely sense relative evapotranspiration outputs in the distal Okavango Delta using enhanced thematic mapper and ground based techniques to help quantify water loss. Much of this work focuses on riparian woodlands which, especially in the distal portion of the Delta, are regarded as being significant in terms of groundwater removal by transpiration. This was confirmed as vegetation cover mapping led to the identification of two riparian classes which, by association with high resistivity aeromagnetic data, were found to be rooted in near surface fresh groundwater. This paper indicates that riparian trees which remain green year long, partly sustain their growth as a result of groundwater uptake. A comparison of frequently flooded and dry floodplains with distinct riparian zones was undertaken using spectral techniques (pixel radiance values and leaf water content indices) to determine whether flooding and lateral groundwater flow stimulated growth (and therefore transpiration rate) following dormancy. Results indicate a basic similarity between the two systems with mixed evidence of assumed leaf growth. Related phenological observations in the riparian zone of the dry floodplain show that renewal of leaf growth is primarily related to rainfall, not flood events in the distal Delta. The results of this work should help effect both surface and groundwater management in the vicinity of population centres in the distal Delta.  相似文献   

流体包裹体方法在油气源追踪对比中的应用——以四川盆地碳酸盐岩大型气田为例   总被引：14，自引：4，他引：14  

陶士振张宝民  赵长毅 《岩石学报》2003,19(2):327-336

本文运用流体包裹体方法，基于薄片观察和岩矿学研究，探讨了四川盆地碳酸盐岩大型气田的气源。首先对包裹体的生源属性、多期捕获和后生变化进行了精细的鉴别分析。在此基础上，通过成岩自生矿物微量元素、包裹体相组成、均一温度、初熔温度等参数鉴别多期演化的油气充注。通过烃类包裹体化学成分初步鉴别出煤成气和油型气。根据烃类包裹体的相组成鉴别有机质可能来源于腐泥型源岩还是腐殖型源岩。最后根据同期包裹体生物标志物确定某一期次的油气所对应的烃源层。结果表明研究成果符合地质实际，为传统的油气源追踪对比研究提供了一个重要有效的辅助方法。  相似文献   

醋酸丁酯萃取-无火焰原子吸收法测定化探样品中痕量金   总被引：3，自引：0，他引：3  

刘菊琴  杨永理  韦山桃 《矿产与地质》2003,17(3):261-262,F003

在KBr存在下,用小体积醋酸丁酯萃取金后,用无火焰原子吸收法测定化探样品中痕量金的分析方法较化学富集光谱法具灵敏度高(检出下限可达0.05×10-9)、精度好、简便快速、成本低等优点.通过批量化探样的检验,证明该方法足已满足化探样品对金的测定要求.  相似文献   

云南省癌死亡率与土壤环境中化学元素的关系   总被引：3，自引：0，他引：3  

曾昭华  曾雪萍 《云南地质》2003,22(4):395-402

癌病严重危害人类生命。研究表明：土壤环境中微量元素与肿病发生发展以及治疗相关，个别地区的地方病与元素含量关系密切。对土壤中元素含量研究证实：云南癌死亡率低于全国平均水平。文章详细讨论云南9种频发、52种常见癌症与元素的关系。  相似文献